Decoction Mashing

Discussion in 'Homebrewing' started by OldBrewer, Dec 13, 2020.

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  1. OldBrewer

    OldBrewer Maven (1,385) Jan 13, 2016 Canada (ON)

    This is a more difficult question for those who do decoction mashes.

    There are several approaches to decoction mashes. Most of the ones pertaining to a single decoction involve pulling a thick decoction during the early stages of mashing, bringing it to a boil, boiling it for 10-30 minutes and adding it back to the mash.

    Another approach involves doing the mas first and then pulling the decoction, boiling it and adding it back to the mas for a mash-out.

    With the first approach, the grain hasn't been mashed yet, so they contain starch while doing the decoction. With the second approach, the grains have already been mashed, so contain a lot of sugars.

    Will there be a difference in taste by using the two different approaches? In other words, do you get different Maillard products using a decoction with grains containing starch, as opposed to using grains containing sugar?

    I haven't been able to find any documentation on this.
     
  2. PortLargo

    PortLargo Pooh-Bah (1,831) Oct 19, 2012 Florida
    Pooh-Bah

    What you have described is a two-step decoction, and each step has a different function. The first step is where the Maillard reaction will occur. If desired, your mash-out water could be heated separately and added, that would be a one-step decoc. Or the liquid drained, boiled and re-added (as you described, two-step). This step is largely just to reach the mash-out temp, not to measurably effect taste and is not normally used by itself. Sometimes you'll see reference to a three-step decoction, where a second portion is pulled/boiled/re-added to give a stepped up mash temp (equivalent to a step infusion mash).

    Remember, the decoction process evolved before thermometers were in wide use . . . boiling temps could be observed and that's the key in hitting your mash steps.

    Here's an excellent discussion, to include youtube videoes:
    http://braukaiser.com/wiki/index.php/Decoction_Mashing
     
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  3. JackHorzempa

    JackHorzempa Grand Pooh-Bah (3,375) Dec 15, 2005 Pennsylvania
    Society Pooh-Bah

    Waaay back in the day decoction mashing was employed since the thermometer was not invented yet and the brewers knew that they could achieve a proper step mash via decoction. The step mash was employed to activate the various enzymes at the varying temperatures and this is especially important when utilizing undermodified malts. And yes the boiling process would develop Maillard reactions and for the case of Pilsner Urquell carmelization would occur due to direct heat boiling at very high temperatures (600 °C).

    Even today at Pilsner Urquell a triple decoction process is employed to conduct a mash of varying temperature steps:

    • The mash (malt & water) is first brought to a temperature of 95 °F and then sits for about 20 minutes; this is referred to as an acid rest.
    • A portion of the liquid and some malt is extracted from the mash and boiled
    • This boiled portion is returned to the mash vessel bringing the temperature in the vessel to127 °F. This is permitted to sit for about 30 – 45 minutes. This is a protein rest which activates proteinase and peptidase enzymes.
    • A second portion of liquid and some malt is extracted and boiled.
    • This boiled portion is returned to the mash vessel bringing the temperature in the vessel to 143 °F. This is permitted to sit for about 30 – 45 minutes. This is the saccharification rest which activates the Beta-amylase enzyme and to a lesser degrees the Alpha-amylase enzyme.
    • A third portion of liquid and some malt is extracted and boiled.
    • This boiled portion is returned to the mash vessel bringing the temperature in the vessel to 163 °F. This is permitted to sit for about 10 – 15 minutes. This final step is acts as the mash out.

      Cheers!
     
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  4. OldBrewer

    OldBrewer Maven (1,385) Jan 13, 2016 Canada (ON)

    Thanks @PortLargo. Perhaps I did not explain the procedure carefully enough.

    In both approaches, I'm only using a saccharification rest since I'm using modified grains.

    In the first approach, as soon as the mash is at the saccharification temperature, about 1/3 of the thick mash is pulled out and separately brought to a boil and boiled from 10-30 minutes (decoction). This part of the mash has not been converted so the grains contain mostly starch. The rest of the mash continues at the saccharification until the decoction mash has finished boiling and is added back to bring it up to mash-out temperature (about 168 F).

    In the second approach, the entire mash is allowed to continue at saccharification temperature for about 45 minutes. At that point (much of the conversion will have taken place and the grains will contain sugars), about 1/3 of the mash is taken out, brought to a boil and boiled for 10-30 minutes (decoction). Once it has finished boiling, it is added to the rest of the mash which brings it up to the mash-out temperature.

    According to online documentation, this is considered a "Single Decoction".

    So, the main difference between the two approaches is that in one, the decoction uses grain that has not been converted (starch), and the other uses grain that has been converted (sugar).

    So the question is, will there be a difference (in terms of Maillard products which affect the taste) between the two approaches? Does the sugar content in the decoction approach using mashed grains change the amount or nature of the overall Mailard products as compared to the decoction approach using unmashed grains?
     
  5. OldBrewer

    OldBrewer Maven (1,385) Jan 13, 2016 Canada (ON)

    Thanks, Jack. I agree that step mashing has largely replaced decoction mashing because of the availability of thermometers.

    However, and I know this is often debated with some passion, I do not believe that step mashing will give you the same flavors as will decoction mashing. I believe you will obtain far more Maillard products by using decoction mashing than you will get by doing step mashing. During a step mashing process, nothing is boiled or heated to a high temperature.

    I also know that many people cannot discern the taste of Maillard products. Some who can, often mistake it for diacetyl (including high-ranking beer judges). I am highly sensitive to them and enjoy them immensely. For me, it really "adds" to a lager and gives it that extra "European" polish. Some people claim you can achieve the same effect by adding Melanoidin, Vienna or Munich malt. While these all add some of that "Maillard" taste, it never seems quite the same - I've tried them (Melanoidin malt comes closest).

    Thus my question was not about step mashing versus decoction mashing, but about the difference in Maillard products if one were to do a decoction with unmashed grains versus mashed grains (i.e. how much difference to the Maillard products does the sugar content contribute?).
     
  6. JackHorzempa

    JackHorzempa Grand Pooh-Bah (3,375) Dec 15, 2005 Pennsylvania
    Society Pooh-Bah

    My above post was not solely about the aspect of step mashing. Did you read the part where I stated:

    "And yes the boiling process would develop Maillard reactions and for the case of Pilsner Urquell carmelization would occur due to direct heat boiling at very high temperatures (600 °C)."

    If you are looking to recreate a beer like Pilsner Urquell it is not just the chemistry of Maillard reactions which is taking place.

    Cheers!
     
  7. PortLargo

    PortLargo Pooh-Bah (1,831) Oct 19, 2012 Florida
    Pooh-Bah

    This will probably work, but it's not the traditional method. I would be suspicious of the intensity of Maillard reactions doing this...not saying it won't occur, just saying it may be a problem. The old-style method is to have the entire mash brought up to an acid or protein rest (some debate on which), then pull your 1/3 to boil and then back to the Master Mash. It is imperative that this first decoc (1/3'ish) be allowed to "rest" at a sacch temp (150 - 156) for 20 minutes or so to allow for some conversion. Once it's boiled it will all be denatured. This is the portion (the 1/3'ish) that's giving you the Maillard goodies. I suppose if you let the entire mash rest at sacch temp for 20 minutes, then pulled/boiled you would get desirable results.

    In your second approach I'm even more suspicious about getting Maillard reactions. Again this is not a normal decoc profile . . . pretty sure all the grain will be very near converted/denatured at this point. It can be used to hit your temps, but is not normally used this way. The traditional mash-out decoc is to drain the wort only, bring it to a boil, then add back to hit your MO temp.

    These profiles are discussed in detail in the link in my first post. But to answer your original question, I don't know.

    I used to think the same thing and did a lot of decoction mashing. Background: I regularly brewed Rauchbier using a double D. It was entered in the local comps in Miami and always won a gold medal, year after year. After a while I stopped entering because it was pointless, it always took top place. It sounds like bragging but my point is I had the process down PDG. It compared favorably to Schlenkerla, so not much room for improvement. Then I did a true A - B test: Brewed the standard Rauchy using a DD, then brewed the next day with a single mash infusion. Same yeast, hops, grain . . . fermented/larger'ed side by side. In a true triangle test the results were only slightly noticeable, we all agreed that unless side by side there was no difference. Two of three tasters picked the infusion brew as the better (but again only slightly). So I no longer decoc.
     
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  8. OldBrewer

    OldBrewer Maven (1,385) Jan 13, 2016 Canada (ON)

    Yes, I did, but it did not at all address my question. I know boiling produces Maillard reactions, but once again my question is will those Maillard products be different if you boil unmashed grains versus mashed grains. I don't know how I can say it more simply.
     
  9. beershrine

    beershrine Pundit (819) May 29, 2004 Idaho

    I step mash every beer, temps- 122º - 144º - 160º

    get it done as easy as an infusion mash.
     
  10. OldBrewer

    OldBrewer Maven (1,385) Jan 13, 2016 Canada (ON)

    Yes, it's not the traditional approach. but is one that was recommended by an expert in German brewing - Kai Troester. See:

    https://braukaiser.com/wiki/index.php/Decoction_Mashing Get Outlook for Android

    I'm using modified grains, so the acid and protein rests are not necessary. But I agree that this approach will not likely produce results as good as the second approach. Without the conversion, I can't see how any significant amount of Maillard products can be produced.

    This is an approach that was recommended by an expert in German brewing - Kai Troester. See:

    https://braukaiser.com/wiki/index.php/Decoction_Mashing Get Outlook for Android

    He mentions including a protein rest if desired, but says it's not required for well-modified malts. This approach is discussed in detail in the link in my first post (see "Single Decoction").
    I have used a similar process before, and know that it does work. I have not tried the first approach.

    It likely makes little difference in a strong-tasting beer like Schlenkerla. The tastes from the Maillard products are somewhat subtle, but noticeable in delicate, lighter lagers like Pilsners.

    As an aside, how did you get the real "smokiness" of a Schlenkerla? I've tried making it with 100% smoked malt, but the smokiness was nowhere near to the smokiness of the original. Did you smoke the malt yourself?
     
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  11. OldBrewer

    OldBrewer Maven (1,385) Jan 13, 2016 Canada (ON)

    But step mashing doesn't produce Maillard products of any significance.
     
  12. PortLargo

    PortLargo Pooh-Bah (1,831) Oct 19, 2012 Florida
    Pooh-Bah

    The secret is fresh smoked malt, as smokiness drops off pretty fast. Those dudes in Bamberg just drive across town to get it from Weyermann. In a LHBS in the US it may have been sitting around months (year?) and no retailer will tell you their smoked malt is old and crappy. A local brew shop lets me tag on to his commercial orders so I cut out a distribution step. Also, was originally radicalized that only Weyermann made a proper rauchmalz, but last time I used Bestmalz (Heidelberg) and it was just as good . . . but has to be fresh.
     
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  13. OldBrewer

    OldBrewer Maven (1,385) Jan 13, 2016 Canada (ON)

    Thanks - that explains it! The smoked malt I used must have been old.
     
  14. beershrine

    beershrine Pundit (819) May 29, 2004 Idaho

    Heating a mash tun can produce the Maillard reaction it just depends if your going to mix the mash while blast heating. A fixed thermometer in the tun will be inaccurate. Industrial brewing is entirely different than our systems. Keeping the color light with a pilsner will be the issue.
     
  15. OldBrewer

    OldBrewer Maven (1,385) Jan 13, 2016 Canada (ON)

    Yes, with decoction brewing that is an issue - it will definitely darken somewhat. But in my experience, a single decoction does not darken the beer too much, especially if you stir constantly (it's the scorching in the bottom of the pot that causes most of the darkening). You can also darken lagers by lengthy boils.
     
  16. beershrine

    beershrine Pundit (819) May 29, 2004 Idaho

    True, I stay away from too much stirring just a couple swirls and cuts. A raised mash screen is the way to go with liquid underneath, Thanks
     
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  17. hopfenunmaltz

    hopfenunmaltz Pooh-Bah (2,635) Jun 8, 2005 Michigan
    Pooh-Bah

    Ah, no FFS.

    Schlenkerla and Spezial malt and kiln their own grains. I've been through Spezial. There are plenty of videos out there about Schlenkerla kilning their malt over Beechwood.

    Edit - small breweries around Bamberg get Rauchmalz from Weyermann for seasonal smoke beers, but not Schlenkerla or Spezial.
     
    #17 hopfenunmaltz, Dec 16, 2020
    Last edited: Dec 16, 2020
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  18. invertalon

    invertalon Pooh-Bah (2,249) Jan 27, 2009 Ohio
    Pooh-Bah Trader

    This is correct!

    @PortLargo

    "Forward some more to the present day and only two continue to do so: Schlenkerla, and Brauerei Spezial. Both brewers being proud guardians of an ancient process used to create unique woodsmoke flavours from their own bespoke malts...

    In their own kiln, heated directly by a fire fuelled by locally sourced beech logs of course, Schlenkerla produce around 350 tonnes of malt each year in 4 tonne batches, enough to meet their own needs. Their world renowned Märzen, Urbock, and Eiche, are all brewed with a grist of 100% Schlenkerla smoked malt. Only a small percentage of their malt is sourced externally for their Fastenbier and Kräusen beers that contain a blend of smoked and unsmoked malt"

    This was recently posted actually, "The Ancient Art of Schlenkerla"... Can be found here:

    https://www.jamesclay.co.uk/experti...n0l4TW1C28OBoaUGN5i7wxtcPh56F8KE2bBWb_DclYaV0
     
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  19. invertalon

    invertalon Pooh-Bah (2,249) Jan 27, 2009 Ohio
    Pooh-Bah Trader

    On a side note... I brew quite a bit of Rauchbier and have tried most of the commercial available malts and have blended and tried to recreate the intensity and character of what I enjoy in Schlenkerla/Spezial/etc... It wasn't until I start smoking my own malt that I got the depth and smoke character I was really after. It's the only way to go for my Rauchbier these days!
     
  20. PortLargo

    PortLargo Pooh-Bah (1,831) Oct 19, 2012 Florida
    Pooh-Bah

    Do you decoc or infuse?

    Thanks for the history link, very informative. My Rauchy stood up well to Schlenkerla, but there was always that last little "umph" that it couldn't get over. Although my smoked malt was fresh I knew it still had several extra months on it. Now I realize I'll never get the true Sch'y level without chopping down some beechwood trees. I do applaud your quest to create the original . . . for me smoking my own malt really wouldn't be worth the one extra point (maybe?). Which base malt did you find produced the best results? Would think this would carry over to non-smoked brews.
     
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