How Beer Evolves in Barrel vs in Bottle?

Discussion in 'Cellaring / Aging Beer' started by Blackmill, Aug 30, 2018.

  1. Blackmill

    Blackmill Initiate (37) Jan 18, 2017 California

    I've been trying to find an answer to this for a while.

    How does beer age differently in oak versus in the bottle?

    Example: A wild ale aged 3 years in oak versus the same wild ale bottled after 1 year and cellared for 2. So, same age, just in different environments.

    With no claims of accuracy this is what I've gathered...
    1. Aging in the barrel will continue to add oak, barrel character, and tannin to the beer.
    2. The barrel allows more air into the beer than a bottle, so the same beer aged longer in a barrel will have experienced more oxidation, even if it isn't noticeable.
    3. Brett and other bacteria may ferment barrel sugars that are present. Hence, the same beer aged longer in a barrel may have higher ABV, or more yeast character.

    What other differences are there? Especially with regards to fermentation? Has any one done an experiment similar to the mentioned example?

    Thanks!
     
  2. Lazhal

    Lazhal Devotee (446) Mar 13, 2011 Michigan
    Trader

    Patrick Dawson addresses this some in his book Vintage Beer. I simply don't remember it well enough to give you an accurate answer. It's a good read, especially since you seem interested in some of the finer technical points. I do recommend picking it up.
     
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  3. NeroFiddled

    NeroFiddled Poo-Bah (10,282) Jul 8, 2002 Pennsylvania
    Premium Trader

    Once beer goes into the bottle it basically stops evolving unless we're talking about bottle-conditioning. Even then, there's only so much that can go on. Evolving? Or devolving then becomes the question.

    In a barrel there are hundreds of chemical reactions going on that are far to complicated to go into here, let alone getting into the differences between fermenting in wood and aging in wood, and working with things like Brett. and Pediococcus. As for the 3 things you've listed I'd say you've got 1 and 2 right, but number 3 is much more complex.

    There are a few books out on the subject but information is continually coming out on these concepts as well. Maybe one day there will be a comprehensive source but for right now you'll have to scrabble together what you can and read it all.
     
  4. Sabtos

    Sabtos Poo-Bah (5,048) Dec 15, 2015 Ohio
    Trader

    Yes, oak breathes, expanding and contracting with temperature changes, every single day, causing oxidation, in a more favorable manner than the sort of oxidation you want to avoid in packaged product, but still oxidation all the same. For clean beers especially, it's a risky process and why many breweries still steer away from it.
     
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  5. Blackmill

    Blackmill Initiate (37) Jan 18, 2017 California

    Do you mean the beer stops evolving because there won't be sugars for the yeast to ferment? I remember reading (here) that brett will eat compounds other than wort sugars, like esters, phenols, and hop compounds. I figured that meant a beer with brett will still evolve, even if there are no sugars to ferment, but maybe that's misinformation.
     
  6. NeroFiddled

    NeroFiddled Poo-Bah (10,282) Jul 8, 2002 Pennsylvania
    Premium Trader

    If the beer is bottle-conditioned it will ferment the residual or added sugars creating carbonation and then giving some extra flavor via the yeast itself. (With any bottled beer that has yeast in it, if the yeast has sedimented properly, pour off a clear glass and then rouse the yeast and pour a glass of that and taste them side by side. They will not taste the same.) At that point it will act just like any other bottled beer and basically start to deteriorate due to oxidation. It may be "evolving", but is it getting better or worse? That's a question that a lot of people who age beer have to grapple with. Sometimes there's a pleasant change, perhaps in perceived maltiness and softening of the bitterness, or perhaps in the smoothing of some of the hotter alcohols. Other times the beer just loses life and becomes muddled and dull, or even noticeably oxidized with papery or cardboard notes.

    Brettanomyces on the other hand, although also a yeast, is totally different and gives off interesting phenols and esters - it does not eat them although it may transform them. It can eat some additional sugar, however, given time. Brett also takes much longer to ferment than a standard brewers yeast, and will most likely still be working for some time after bottling. Very slowly, but yes, still working. There are other factors at work as well: how much oxygen the Brett has to work with, and the possible changing pH of the beer. What I've referred to so far covers fermenting in stainless steel, fermenting in wood is completely different, and apart from other microflora that's probably in the wood, the environment is quite different and complicated. One example would be that in wood there will be oxygen coming available to the Brett that it won't have in a fermenter, keg, or bottle.

    There's a basic article about Brett and souring critters here:
    https://draftmag.com/brettanomyces-lactobacillus-pediococcus-beer/
     
    #6 NeroFiddled, Sep 2, 2018
    Last edited: Sep 2, 2018
  7. Blackmill

    Blackmill Initiate (37) Jan 18, 2017 California

    Thanks for the detailed reply. I'll take a look at that article.
     
  8. EvenMoreJesus

    EvenMoreJesus Champion (833) Jun 8, 2017 Pennsylvania
    Premium Trader

    Are you just curious about mixed microbe fermentations or about all barrel fermentations?

    If we're just talking about mixed microbe fermentations, most of the barrels that are used to carry out those are neutral barrelage. In other words, there will not be very much, if any, barrel character to impart. This is why traditional lambic, although aged for an extended period of time in wood, lacks wood character.

    Oxidation, in mixed microbe fermentations, is the least of your worries. Brettanomyces sp. when in an environment with oxygen will produce acetic acid and also esterify that acetic acid, in the presence of ethly alcohol, into ethyl acetate, which, at higher concentrations, give the beer an acetone/nail polish remover character.

    Even though Brett sp. can ferment cellobiose due to glucoside enzyme activity, probably not, as most ester formation occurs in the log phase of fermentation and phenol formation happens secondary to phenolic precursors (mostly hydroxycinnamic acids) and has to do with the strength of the species' decarboxylase and reductase enzymes and the amount of cellobiose fermented will not be sufficient to change the ABV of the beer in any but the most miniscule amounts.

    IMO, outside of classic lambic and Methode Traditionnelle fermentations, time in the barrel should be limited to the completion of fermentation, which can be as quick as 8 weeks because of the reasons stated above.
     
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  9. Blackmill

    Blackmill Initiate (37) Jan 18, 2017 California

    I'm most curious about mixed microbe fermentations. Many of my favorite beers are mixed culture.

    Is this also a reason to avoid cellaring bottles that have Brett in them? I imagine bottles expose the beer to less oxygen than a barrel, though, so maybe not.

    Are classic lambic and MT fermentations more robust to time in barrel because they use aged hops? Or does the fermentation itself imbue some immunity to acidification?
     
  10. EvenMoreJesus

    EvenMoreJesus Champion (833) Jun 8, 2017 Pennsylvania
    Premium Trader

    Cool.

    Na. Once you've got the beer into the package, there is a finite amount of oxygen to which the liquid can be exposed. Even though the closure is permeable, it's not THAT permeable.

    The hops will give you two major things: inhibition of unwanted microbes like enteric species and some lactic acid bacteria like lactobacillus and phenolic precursors especially caffeic acid which is a precursor to vinyl and ethyl catechol.

    The thing that prevents above threshold acetic acid and ethyl acetate production in long term barrel aging is the barrel itself. If it has a low ingress and is closed properly, it is a good vessel for long term aging. If not, well, not so much.
     
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