Questions on Adjusting pH Up Post-Fermentation

Discussion in 'Homebrewing' started by scurvy311, Sep 21, 2017.

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  1. scurvy311

    scurvy311 Savant (1,135) Dec 3, 2005 Louisiana

    I have an Imperial Sweet Stout fermenting that I've perfected over the years. I shoot for a mash pH around 5.5-5.6, which I'm normally in the ballpark. This batch using my Milwaukee ph65 meter read 5.18. I went and calibrated it and resampled and it read 5.16. Only dif in recipe was base malt. I normally use standard MO from morebeer and this time I used morebeer's Gleneagles MO. I didn't think to adjust pH between mash and boil.

    Could the dif base malts have caused that big of a swing between 2 dif MOs? I use brewcipher and just used the settings for the MO in the grain table.
     
  2. EvenMoreJesus

    EvenMoreJesus Initiate (0) Jun 8, 2017 Pennsylvania

    Your mash pH, boil pH, and post-fermentation pH will all be different. As long as you get good starch conversion in your mashtun, I can't think of a reason why you'd want to alter it post-fermentation.

    No differences in water, btw?
     
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  3. scurvy311

    scurvy311 Savant (1,135) Dec 3, 2005 Louisiana

    Nope. Distilled, used calcium chloride and gypsum to get the chloride/sulphate ratio and slaked lime to dial in the pH. I nailed all numbers otherwise. This is prob my 6-8 batch and is one of my more reliable brews. Thx for the reply.
     
  4. Tebuken

    Tebuken Initiate (0) Jun 6, 2009 Argentina

    Some carbonates would be advisable to add to your mash to raise ph a bit (5.4-5.5) and to round flavor a bit too. I would add about 4 grs of CaCO(calcium Carbonate) for 5 gals of beer
     
  5. scurvy311

    scurvy311 Savant (1,135) Dec 3, 2005 Louisiana

    To the finished beer or next time in the mash?
     
  6. Tebuken

    Tebuken Initiate (0) Jun 6, 2009 Argentina

    To the mash
     
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  7. VikeMan

    VikeMan Grand Pooh-Bah (3,067) Jul 12, 2009 Pennsylvania
    Pooh-Bah

    You could increase the pH of the finished beer by adding some more slaked lime or some baking soda, but why do you want to? Does it taste tart? What's the current pH?
     
  8. scurvy311

    scurvy311 Savant (1,135) Dec 3, 2005 Louisiana

    It's actively fermenting right now. I don't plan on doing anything until I can taste it. I was planning on taking a pH sample in a week or 2 when it's finished.
     
  9. hopfenunmaltz

    hopfenunmaltz Pooh-Bah (2,635) Jun 8, 2005 Michigan
    Pooh-Bah

    Base malts can have different resulting pH, due to lovibond differences. I had a bag from a lot of Best Pils that was contaminated with acidulated Malt, that came out about 0.25 lowered than expected.

    If I was not so lazy I would measure out a small sample of the grist the night before, mash it with my treated RO water, and determine if the pH matches the prediction.

    You can adjust the finished beer. Go slow with additions, as you can't take them out, and it is just more work to have to go back the other way.
     
  10. telejunkie

    telejunkie Savant (1,107) Sep 14, 2007 Vermont

    Hmm...I just can't imagine that two MOs would swing that far...

    Yeast will be a big player in final pH of the beer. I would definitely hold off before making any changes. I often prefer a more sour-sided stout personally (think Guiness FES)....especially to counter the sweetness you're going to have in a sweet stout.
     
  11. GormBrewhouse

    GormBrewhouse Pooh-Bah (2,111) Jun 24, 2015 Vermont
    Pooh-Bah

    I have noticed a difference in taste between crisp and Simpsons marris otter. Never measured the pH.
     
  12. VikeMan

    VikeMan Grand Pooh-Bah (3,067) Jul 12, 2009 Pennsylvania
    Pooh-Bah

    The thing to remember about Maris Otter is that the name actually refers to the variety of barley, which can be kilned to whatever degree the maltster wants. So some are darker (more highly kilned) than others. IIRC, someone even makes a Maris Otter derived malt that's is extremely low kilned, like a pilsner malt.

    If you try a new Maris Otter malt and it gives a much lower pH than you're used too, it's probably more highly kilned than a typical Simpsons/Crisp/Fawcett M.O.

    @scurvy311 do you happen to know the Lovibond rating of the M.O. you used? Since you're using BrewCipher, you could change the Lovibond on the M.O. row on the Malt tab, or add a new row on the malt tab for this particular M.O.

    That said, color isn't the end of the story. Sometimes you just have to dial in by trial and error when using a grain that doesn't behave as expected.
     
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  13. JackHorzempa

    JackHorzempa Grand Pooh-Bah (3,375) Dec 15, 2005 Pennsylvania
    Society Pooh-Bah

    Below is color data from the MoreBeer website:

    Bairds Maris Otter Pale Ale Malt: 2.5 – 3.5 °L

    Thomas Fawcett Maris Otter Pale Ale Malt: 2.3 – 3.0 °L

    UK Gleneagles Maris Otter - Crisp Malting: 3.8 °L

    So, the Gleneagles version is the darkest and it would be reasonable to expect it will acidify the mash (i.e., lower mash pH value) more than the other versions.

    Cheers!
     
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  14. Mohican88

    Mohican88 Initiate (0) Jan 20, 2010 Ohio

    This definitely varies by lot as well. The most recent bag of the Gleneagles I just used up was 4.5L, and the bag I just bought is 4.0L. Also, of note it's not called Gleneagles anymore, it's No. 19.
     
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  15. pweis909

    pweis909 Grand Pooh-Bah (3,250) Aug 13, 2005 Wisconsin
    Pooh-Bah

    The magnitude of the pH difference is surprising to me. Attribution of that to the couple degees Lovibond in the kilning of the Glen Eagle MO seems like a stretch. I think there is probably enough batch to batch variation in kilning that we would see this kind of problem more frequently than we do, if a couple L made a big diff.

    My initial reaction was that maybe you were supplied a different malt than you think, sort of like @hopfenunmalz experience with accidentally getting acid malt. The other thought was you mismeasured your chemical additions. For example, maybe the slaked lime has absorbed some water and your mass represents a lower amount of lime than you think. I don't know how hygroscopic slaked lime is, off-hand. Picking on that one because I think it is the one where a small mistake could lead to the largest impact. Just speculation.
     
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  16. scurvy311

    scurvy311 Savant (1,135) Dec 3, 2005 Louisiana

    About to transfer, recalibrated my pH meter and I'm reading 4.7pH. It doesn't taste tart, but the uncarbed beer taste a little flabby. I think I'll just leave it alone. When I adjust the pH with slaked lime or baking soda the Ca or Na gets thrown way out of comfort.
     
  17. VikeMan

    VikeMan Grand Pooh-Bah (3,067) Jul 12, 2009 Pennsylvania
    Pooh-Bah

    If anything, 4.7 is a little on the high side for a finished beer. I would definitely not try to increase it.
     
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