Saison issue / yeast question

Discussion in 'Homebrewing' started by d3kalb, Mar 25, 2015.

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  1. d3kalb

    d3kalb Aspirant (275) May 3, 2012 California

    Apologies in advance for the length of this.

    Background: A few weeks back I had a big double brew day where I brewed 16 gallons of saison that I split four ways. One with yeast bay wallonian, one with yeast bay saison blend, one with farmhouse sour and one with sour dregs and 565. Before this I've brewed 6 saison batches in the last few months or so all with very similar grain bills except for acidulated malt which I added this time around. All of my boil times have always been 60 minutes of a strong rolling boil. I pitched the yeasts at 72 and kept them in the low to mid 70's for the entire time they have been in their carboys.

    And now the problem. Starting right from my first check after fermentation died down 3-4 days in, the two clean YB batches had a sulfuric (DMS?) aroma. I let them sit for almost another two weeks with fermentation having totally stopped after the first week and transferred one to a keg yesterday.

    1. Happy to include any important information I may have left out, but is this likely DMS that I'm smelling? Either way my boil time will never be less than 75 minutes in the future, just in case.
    2. If not what else could it be? Am I maybe overly sensitive to this and it's actually not as bad as it seems?
    3. Will co2 possibly push this away after some time cold and carbonating?
    4. I kept the yeast because I'm convinced this is a problem with my process and therefore want to be sure that what seems like my brewing problems won't affect the yeast in any way if I were to repitch in the future.
     
  2. pweis909

    pweis909 Grand Pooh-Bah (3,250) Aug 13, 2005 Wisconsin
    Pooh-Bah

    Yeasts can produce sulfuric odors that are not DMS. Farty rotten egg type aromas, for instance. It can be somewhat strain dependent. They can dissipate over time via out gassing or yeast metabolism. I'm not sure I ever detected DMS in a beer, but have definitely encounter these reduced sulfur aromas during fermentation and they have always gone away. I think they are common in lagers and perhaps have something to do with yeast metabolism under cooler temps. However, for saison, I'd guess you fermented warm, so maybe not the same thing? All just speculation. Nothing you can do but RDWHAHB.
     
  3. DrMindbender

    DrMindbender Initiate (0) Jul 13, 2014 South Carolina

    Berliner Weisse are known for sulfuric smells during fermentation, but I never taste farts in a Berliner...I think you'll be fine.
     
    Lukass likes this.
  4. JackHorzempa

    JackHorzempa Grand Pooh-Bah (3,375) Dec 15, 2005 Pennsylvania
    Society Pooh-Bah

    There are a number of sulfur compounds that can be produced during beer making. As has already been discussed it is possible that some sulfur compounds will be produced during fermentation but they will dissipate (e.g., get ‘blown out’ by CO2) during the fermentation process. There sulfur compounds are only a genuine issue if they exist in the finished beer.

    For anybody who wants to know what DMS smells/tastes like, buy yourself a bottle of Rolling Rock. Rolling Rock has a significant amount of DMS and it is there on purpose.

    Below is a list of sulfur compounds that are sometimes perceptible in beer (depending on the compound level/amount) along with common descriptors:

    Dimethyl Sulfide (DMS): cooked corn, creamed corn, vegetal

    Sulfur Dioxide (SO2): struck match

    Hydrogen Sulfide (H2S): low level: onion/garlic, higher levels: burnt rubber. Sometimes also described as rotten egg.

    Mercaptan (3-methylbut-2-ene-1-thiol): the lightstruck formed compound that is described as skunky, catty, feral, polecat

    Dimethyl Trisulphide (DMTS): onion/garlic

    Cheers!
     
    CASK1 likes this.
  5. hopfenunmaltz

    hopfenunmaltz Pooh-Bah (2,635) Jun 8, 2005 Michigan
    Pooh-Bah

    Add 4MMP to that.
     
    JackHorzempa likes this.
  6. JackHorzempa

    JackHorzempa Grand Pooh-Bah (3,375) Dec 15, 2005 Pennsylvania
    Society Pooh-Bah

    Will do! I knew that 4MMP was a thiol but I just 'learned' that thiols are sulfur compounds. You learn something new every day!

    Cheers!

    P.S. I should have pieced that together since Mercaptan is a thiol.:flushed:
     
  7. VikeMan

    VikeMan Grand Pooh-Bah (3,067) Jul 12, 2009 Pennsylvania
    Pooh-Bah

    I thought Mercaptan is a synonym for Thiols in general, not specifically 3-methylbut-2-ene-1-thiol. Point being there are other Mercaptans besides the skunky lightstruck one. Though I suspect they'd all be bad news for beer.
     
    Brew_Betty likes this.
  8. JackHorzempa

    JackHorzempa Grand Pooh-Bah (3,375) Dec 15, 2005 Pennsylvania
    Society Pooh-Bah

    “Lightstruck character is caused by a photochemical reaction where visible or ultraviolet light (wavelength below 520 nm) makes riboflavin in the beer react with and break down hop-derived, sulfur-containing isohumulones (isomerized alpha acids). This liberates 3-methylbut-2-ene-1-thiol, a mercaptan, a compound detectable at just a few parts per billion, which is similar to the active ingredient in skunk musk.”

    More science can be found here: https://beersensoryscience.wordpress.com/2011/03/17/lightstruck/

    Cheers!
     
  9. Brew_Betty

    Brew_Betty Initiate (0) Jan 5, 2015 Wisconsin

    Some yeasts produce a sulfur aroma and it usually disappears by the time you are ready to drink it. Saisons don't need to be consumed fresh. My bet is the sulfur will be gone after a few weeks of being in the keg. I have never had a saison yeast make sulfur smells and have never used Yeast Bay yeast. It could be normal for the strain(s). The Yeast Bay guy lurks here.

    Ask @Biobrewer what the deal is. Wait...I just did.
     
  10. SFACRKnight

    SFACRKnight Grand Pooh-Bah (3,348) Jan 20, 2012 Colorado
    Pooh-Bah Trader

    Just got done with primary on my HF dreg saison, and I co pitched the stepped up dregs with wyeast Forbidden Fruit. It REEEEEEEEEKED like rotten eggs for two weeks straight, even left a mineral type ring on my 3 piece airlock where it was off gassing. I sampled it at the time it went into the carboy for secondary and there are no signs of sulfur in the beer. It's sour and bready, but no sulfur.
     
  11. Brew_Betty

    Brew_Betty Initiate (0) Jan 5, 2015 Wisconsin

    How can we be sure you weren't smelling your dirty mustache two weeks in a row? Forbidden Fruit doesn't make sulfur and there is no possible way HF dregs can produce anything less than amazing ever. Just a few weeks ago, you were telling us how magical the HF dregs starter was smelling. Therefore, your anecdotal experience is currently classified as suspicious!
     
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  12. pweis909

    pweis909 Grand Pooh-Bah (3,250) Aug 13, 2005 Wisconsin
    Pooh-Bah

    It's been about 25 years since I shared a bucket of Rocks with friend. I didn't know enough to look for it back then, but there was nothing obvious to me. In contrast, I have known skunk every since I have known Becks, and I think I have tasted acetaldehyde from Budweiser, both about the same era. Maybe I am insensitive to DMS in beer.
     
  13. VikeMan

    VikeMan Grand Pooh-Bah (3,067) Jul 12, 2009 Pennsylvania
    Pooh-Bah

    DMS is the reason why Rolling Rock is the one beer on the planet that I will not drink under any circumstances. Just awful. I didn't know back in the day that it was DMS. I just knew it tasted like vegetable soup, with extra corn. Rolling Rock helped me stay very sober back in my college days, because it was often what everyone was drinking.
     
  14. JackHorzempa

    JackHorzempa Grand Pooh-Bah (3,375) Dec 15, 2005 Pennsylvania
    Society Pooh-Bah

    Peter,

    The green apple flavor in Budweiser is an ester that the Budweiser yeast produces. Budweiser has a very low level of acetaldehyde.

    I suppose it is possible that some folks (you?) are insensitive to DMS but I have not read anything about that. I have read that something like 20% of people are insensitive to diacetyl in beer.

    Cheers!
     
  15. Brew_Betty

    Brew_Betty Initiate (0) Jan 5, 2015 Wisconsin

    I don't even think they ship Rolling Rock to Illinois anymore. Turrible beer. Just turrible.
     
  16. pweis909

    pweis909 Grand Pooh-Bah (3,250) Aug 13, 2005 Wisconsin
    Pooh-Bah

    I had read a while ago that they left acetaldehyde behind as a consequence of beechwood aging. Are you busting my myth? Either way, curious that it exists at all. They are the most capable brewers in the world; they can make cleaner beer if they wanted.

    I can definitely taste diacetyl in beer. It ruined a local brew pub for me once.
     
  17. hopfenunmaltz

    hopfenunmaltz Pooh-Bah (2,635) Jun 8, 2005 Michigan
    Pooh-Bah

    The acetaldehyde in Bud is a myth that won't die. They don't release the beer unless it is below threshold for acetaldehyde.

    Read what Mitch Steele has to say, scoll down a little,
    http://hoptripper.com/what-is-quality/
     
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  18. JackHorzempa

    JackHorzempa Grand Pooh-Bah (3,375) Dec 15, 2005 Pennsylvania
    Society Pooh-Bah

    “I had read a while ago that they left acetaldehyde behind as a consequence of beechwood aging. Are you busting my myth?” The acetaldehyde level in Budweiser is very low. If the “myth’ is that Budweiser has perceptible acetaldehyde, then yes I am busting that myth.

    “Either way, curious that it exists at all. They are the most capable brewers in the world; they can make cleaner beer if they wanted.” What exists in Budweiser is an ester that provides an apple like flavor. The reality here is that AB is purposefully producing this flavor vis their selection of yeast strain and fermentation process.

    Cheers!
     
    pweis909 likes this.
  19. sergeantstogie

    sergeantstogie Initiate (0) Nov 16, 2010 Washington

    Any ideas who he means when he said "Not to name any names, but there is one lager brewer who operates in this country whose beer has definite acetaldehyde-and I think it’s a characteristic of their yeast strain"?
     
  20. pweis909

    pweis909 Grand Pooh-Bah (3,250) Aug 13, 2005 Wisconsin
    Pooh-Bah

    Nutz. It appears that once again, I have been duped.
     
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