Water/mash efficiency

Discussion in 'Homebrewing' started by briggssteel, Jun 5, 2012.

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  1. Danielbt

    Danielbt Initiate (0) May 4, 2012 Texas

    Thanks for this tip! Great info, as usual.
     
  2. briggssteel

    briggssteel Initiate (0) Apr 8, 2010 Ohio

    Question. If I use 5.2 mash stabilizer will the use of brewer's salts mess with it making the PH 5.2?
     
  3. hopfenunmaltz

    hopfenunmaltz Pooh-Bah (2,635) Jun 8, 2005 Michigan
    Pooh-Bah

    I use RO water from the local Meijers, and it tested almost ion free. I add salts, using Bru'nwater to calculate what I need to add. The mash pH comes out within 0.1 of the target (last time it was only 0.03 off).

    5.2 stabalizer is one thing I have given up on, I don't need it. If you have very soft water or highly alkaline water it may not help. I trust my pH meter and Brun'nwater to get to my target pH.
     
  4. jokelahoma

    jokelahoma Savant (1,162) May 9, 2004 Missouri


    Like Hopfenunmaltz said, some folks find they don't need 5.2 Stabilizer. I use it, not because I need it necessarily, but for peace of mind.

    As to your question, if you add the right salts based on your beginning water profile and the SRM of the beer you're brewing, I'd think that not only would it not mess with 5.2, it might make it easier for it to work, getting you closer to the magic 5.2 pH. Remember, though, while you are adjusting the mash pH with salts, many of the salts you're adding aren't primarily intended to adjust the mash pH as much as they are to help the flavor and stability of the end product. For example, you can achieve a good 5.2 mash pH with the right malts and still have calcium and/or sulfate at far less than 50 ppm, but your resulting beer will taste dull and lifeless. I had that problem for far too long until I realized my calcium content in my water was way, way too low. The link at http://www.howtobrew.com/section3/chapter15-3.html has a secondary link at the bottom of the page to an Excel spreadsheet by John Palmer that will help you determine which salts, residual alkalinity, etc. [/HTML] Of course, you have to know your beginning levels in order to find it of any use at all. (And one day I'll figure out why this site doesn't take standard HTML code...)

    Like nathanjohnson said above, it can get complex. The more you learn about water chemistry, the more you learn you don't know about water chemistry. Me, I'm lucky to even spell chemistry without a four-letter head start, but Palmer made it a lot easier to figure it out.
     
  5. hopfenunmaltz

    hopfenunmaltz Pooh-Bah (2,635) Jun 8, 2005 Michigan
    Pooh-Bah

    I would like to point out that some say that the optimal pH is in the 5.2 -5.5 range depending on the beer. Higher for darker beers is what Gordon Strong says.
     
  6. Buggies

    Buggies Initiate (0) Jul 4, 2008 Pennsylvania

    This sounds overly complicated. I think it is often the simplest answer that is the key. This thread got keyed into water chemistry. Do you think maybe that it could be more simple? Maybe an issue of mashing and sparging with proper volumes of water? Just seems to me that this post focused on water chemistry rather than diagnosing his process to give advise on all the possible issues.
     
  7. GreenKrusty101

    GreenKrusty101 Initiate (0) Dec 4, 2008 Nevada

    Occam's razor definitely applies here, but part of the problem sometimes is due to posters asking multiple questions and not really knowing how to focus their banner/post, IMHO.
     
  8. jokelahoma

    jokelahoma Savant (1,162) May 9, 2004 Missouri

    Well, one of the initial questions was "what adjustments should I make?", which naturally leads to discussions of water chemistry. I believe most of the questions were answered early on, but that one needed a deeper answer, which led to other questions, and so forth. It isn't unusual for a thread to take a meandering path, just like any conversation.
     
  9. VikeMan

    VikeMan Grand Pooh-Bah (3,067) Jul 12, 2009 Pennsylvania
    Pooh-Bah

    The OP also stated that he thought the water was RO water, and that he wasn't using any additions. This in itself would be generally terrible for AG brewing, regardless of the rest of his process.
     
  10. briggssteel

    briggssteel Initiate (0) Apr 8, 2010 Ohio

    Well I wanted answers to both so I asked both. I had a feeling the RO water I was using wasn't good for brewing because of the lack of minerals thought it might be affecting mash. And since I probably needed to change my water based off of that I wanted to know how to go about doing it. Just trying to squeeze as much knowledge as I can about people smarter than myself about brewing. :slight_smile:
     
  11. briggssteel

    briggssteel Initiate (0) Apr 8, 2010 Ohio

    Here we go. Finally! Calcium looks a little low, and sodium a little high.


    CHEMICAL RESULTS (mg/L) FROM DAILY ANALYSES and MONTHLY COMPOSITE SAMPLES
    DUBLIN ROAD WATER PLANT 2010

    FINISHED WATER JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC AVG
    Total Alkalinity (CaCO3) 63 69 59 57 58 51 49 52 51 56 53 61 57
    Noncarbonate Hardness (CaCO3) 59 53 63 65 63 70 71 69 70 65 67 58 64
    Total Hardness (CaCO3) 122 122 122 121 120 121 121 120 121 120 120 119 121
    Calcium (Ca) 37 35 36 33 34 40 37 35 35 33 33 34 35
    Magnesium (Mg) 7 9 8 9 9 5 7 8 8 9 9 8 8
    Sodium (Na) 80.6 120.1 85.3 68.0 76.1 33.4 55.0 65.2 71.2 80.4 89.0 85.6 75.8
    Potassium (K) 6.7 5.8 5.0 4.2 4.1 5.1 4.9 5.3 5.5 5.4 5.8 6.6 5.4
    Sulfate (SO4) 104.5 114.9 110.9 111.9 128.2 77.5 114.1 126.2 140.4 146.8 163.3 134.9 122.8
    Chloride (Cl) 77 124 79 57 61 34 46 53 58 61 65 63 65
    Fluoride (F) 0.91 0.90 0.91 0.91 0.90 0.89 0.91 0.90 0.92 0.90 0.91 0.90 0.91
    Nitrate (N) 5.1 5.5 4.1 3.3 1.4 5.6 3.7 0.7 <0.5 <0.5 <0.5 7.1 3.0
    Total Phosphate (PO4) 0.42 0.40 0.40 0.40 0.43 0.39 0.41 0.42 0.41 0.41 0.42 0.42 0.41
    Total Dissolved Solids (TDS) 376 370 390 346 387 282 321 337 391 449 415 408 373
    Turbidity (NTU) 0.05 0.06 0.06 0.05 0.08 0.06 0.07 0.06 0.05 0.06 0.05 0.05 0.06
    Color (Pt-Co Units) 0.4 0.6 0.1 0.2 0.3 0.4 0.6 0.5 0.4 0.5 0.1 0.3 0.4
    Conductivity (uS/cm) 650 855 664 584 640 440 534 576 623 657 703 680 634
    pH Value (pH Units) 7.8 7.8 7.8 7.8 7.7 7.8 7.7 7.7 7.7 7.8 7.8 7.8 7.8
    Chlorine-Free 1.50 1.46 1.50 1.52 1.52 1.50 1.57 1.64 1.60 1.61 1.65 1.61 1.56
    Total THM's (ug/L) 20.3 26.2 25.6 45.9 52.2 65.0 55.8 61.7 53.0 38.9 37.0 32.6 42.9
    Total Organic Carbon (TOC) 3.07 2.95 2.03 2.80 2.40 2.47 2.51 2.10 2.10 2.26 2.86 3.05 2.55

    (ug/L) = Parts per Billion
     
  12. jokelahoma

    jokelahoma Savant (1,162) May 9, 2004 Missouri

    That's really not bad water for a starting point for brewing. Your sulfate level may make adding gypsum to up calcium an iffy proposition, unless you're making an IPA or other bitter beer, but your bicarbonate is fairly low, which makes it easy to work with. I wouldn't worry about the sodium level, because it's within range, and you'll only add it if you use baking soda to up bicarbonates, or table salt (non-iodized!) to up chloride. And with your water, if you want to up chloride, use CaCl. Repeat: That's really not bad water at all. Good for pale ales and amber colored beers as it is, although you want your calcium at least 50 ppm. For most beers in the amber range, you may not need to make any large adjustments at all.

    Now read through the Palmer section linked way back at the beginning of this thread (especially the recommended ranges for each mineral), and download his spreadsheet (although some prefer the spreadsheet at http://www.ezwatercalculator.com/ ), plug in your numbers, and you'll see what you can adjust. Just remember that most salts are two minerals, so when you add a salt to change one, you're also changing another (e.g. adding gypsum to add calcium also adds sulfate, and calcium chloride should be self-explanatory).

    One more bit of "help": Unless you have a gram scale, you're probably going to be estimating any salt additions by using measuring spoons. While not exact, an approximation for each is as follows:


    Chalk / CaCO3

    · 1.8 grams per level teaspoon

    Baking Soda / NaHCO3

    · 4.4 grams per level teaspoon

    Gypsum / CaSO4

    · 4.0 grams per level teaspoon

    Calcium Chloride / CaCl2

    · 3.4 grams per level teaspoon

    Epsom Salt / MgSO4

    · 4.5 grams per level teaspoon

    Canning Salt / NaCl

    · 6.0 grams per level teaspoon

    So if you need 2 grams of chalk, you can get by adding a level teaspoon, etc.
     
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  13. briggssteel

    briggssteel Initiate (0) Apr 8, 2010 Ohio

    That sounds awesome. I've read through Palmer's guide and some others. Some questions: Where do you see bicarbonate? Is that the same as total alkalinity? If I add a campden tablet to take out any chlorine flavor will it affect any of the other minerals and how much of the campden tablet do I add for 5 gallons of water?
     
  14. Tebuken

    Tebuken Initiate (0) Jun 6, 2009 Argentina

    Jokelahoma said it, nothing left to say.
     
  15. JimmyTango

    JimmyTango Initiate (0) Aug 1, 2011 California

    I have these same questions regarding my water.
     
  16. Danielbt

    Danielbt Initiate (0) May 4, 2012 Texas

    One tablet is supposed to treat 20 gallons of water, so a quarter tablet. Campden is potassium metabisulphite, so you're adding that, obviously. Minimal, if any, effect, as it's a tiny amount.
     
  17. Tebuken

    Tebuken Initiate (0) Jun 6, 2009 Argentina

    Total alkalinity and bicarbonates are not exactly the same thing or number but it is a very good aproximation,you don´t need the formula to get exactly how much bicarbonates are in your brewing water, it is a negligible difference.
     
  18. GreenKrusty101

    GreenKrusty101 Initiate (0) Dec 4, 2008 Nevada

    Interesting discussion on water chemistry...prompted me to finally look in to it more thoroughly as I am almost ready to fire up my 10 gal system using all RO water.

    I figure a nice middle of the road approach for this is to use 2 tsp gypsum, 3tsp CaCl, and 1tsp baking soda (courtesy of brewersfriend.com/water-chemistry

    I realise my chlorides will be a little high , but not terribly so for not using any chalk.

    Any better ideas? (apologies for thread jack)
     
  19. jokelahoma

    jokelahoma Savant (1,162) May 9, 2004 Missouri

    What Tebuken said. Your total alkalinity is CaCO3 isn't exactly bicarbonate levels, but they'll usually close enough. Palmer's spreadsheet allows you to choose between using HCO3 and Total Alkalinity as CaCO3. So no, bicarbonate isn't listed on your report, but knowing your total alkalinity is a reasonably close approximation.
     
  20. jokelahoma

    jokelahoma Savant (1,162) May 9, 2004 Missouri

    Depends on your mash volume and sparge volume, GreenKrusty, assuming you're adding all your salts to your mash. If you're doing a 5 gallon batch, with, say, a 4 gallon mash and 5 gallons of sparge, well, I'm guessing here, but I'm betting you could get by with about half that amount of both gypsum and CaCl. Note that I'm no expert by any means. Perhaps some of the guys who actually understand chemistry can chime in.
     
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